Electroplating NiW and NiRe alloys as functional alternative coatings
Abstract
for the German version see below
Objectives: The main objective is the development of new electrolytes for the electrochemical deposition of Nickel-Tungsten (NiW) and Nickel-Rhenium (NiRe) functional layers.
Potential applications: The layers will be able to substitute hazardous Chromium (VI) electrolytes widely employed for corrosion and wear resistance. The filling of polymer microstructures will enable the substitution of expensive gold as X-ray absorbing material in medical imaging and non-destructive testing.
Impact and benefits: The introduction of NiW and NiRe as X-ray absorbing material will have a huge impact for the market introduction of a new medical imaging modality called dark-field imaging through which e.g. diseases related to the degradation of lung alveoli such as chronic obstructive pulmonary disease (COPD) can be made detectable in an early stage through classic radiography. The substitution of chrome (VI) contributes significantly to environmental protection and better working condition for employee
*) Quelle: Deutsches Röntgenmuseum: Verleihung der Röntgenplakette 2018. broschuere_roentgen_plakette_pfeiffer_web.pdf Link
German version
Zielsetzungen: Das Hauptziel ist die Entwicklung neuer Elektrolyte für die elektrochemische Abscheidung von Nickel-Wolfram (NiW) und Nickel-Rhenium (NiRe) Funktionsschichten.
Mögliche Anwendungen: Die Schichten können gefährliche Chrom (VI)-Elektrolyte ersetzen, die häufig für die Korrosions- und Verschleißbeständigkeit eingesetzt werden. Die Füllung von Polymermikrostrukturen wird es ermöglichen, teures Gold als röntgenabsorbierendes Material in der medizinischen Bildgebung und bei zerstörungsfreien Prüfungen zu ersetzen.
Auswirkungen und Vorteile: Die Einführung von NiW und NiRe als röntgenabsorbierendes Material wird einen enormen Einfluss auf die Markteinführung einer neuen medizinischen Bildgebungsmethode, der Dunkelfeld-Bildgebung, haben, durch die z. B. Krankheiten, die mit dem Abbau von Lungenbläschen zusammenhängen, wie die chronisch obstruktive Lungenerkrankung (COPD), durch klassische Röntgenaufnahmen in einem frühen Stadium erkennbar gemacht werden können. Die Substitution von Chrom (VI) trägt erheblich zum Umweltschutz und zu besseren Arbeitsbedingungen für die Arbeitnehmer bei.
Project Partners
Mittweida University of Applied Sciences (HSMW) (Coordinator)
Mittweida University is a university of applied sciences in Central Saxony with a strong focus on research and transfer. Founded in 1867 as a technical centre, the state university has more than 7.000 students in five faculties and four research focuses. The transfer of knowledge and technology plays an essential role at Mittweida University, especially through the ambition to establish national and international collaborations and, at the same time, to assume responsibility for regional development.
A transfer strategy was established, which defines four strategic fields of action in knowledge and technology transfer:
- Transfer via cooperations (in particular R&D projects, contract research, transfer projects),
- Transfer via minds (in particular cooperative PhD examination procedures, endowed professorships),
- Transfer via spin-offs and property rights
- Transfer via communication (in particular scientific events and publications).
Relevant expertise: Prof. Köster's working group has years of experience in the field of electroplating. Electrolyte developments including layer characterisation have been successfully carried out in several projects. In addition to galvanic deposition, there are also extensive experience in the field of electroless deposition and the pre-treatment of substrates.
Role in the project: Lead of WP2 and WP6. Beside project coordination, the scientific task in this project is electrolyte and process development, layer characterization as well as the development of bath analysis.
Institut für Korrosionsschutz Dresden GmbH (IKS)
Relevant expertise: As a research service provider, especially for small and medium-sized companies, the IKS conducts industry-related research, development and technology transfer in the field of corrosion, corrosion protection and corrosion analysis. Through the participation of the institute in previous research projects in the field of process engineering and corrosion analysis, the institute has extensive knowledge and experience to carry out the research project applied for and also the specialist knowledge to evaluate the research results.
Role in the project: Lead of WP3. Upscaling of the developed electroplating technology for the deposition of novel and innovative NiW and NiRe layers as alternative for hard chrome and for grid production as alternative for gold, including the substrate pre-treatments as well the design of the electrodes and sample holders; characterisation of the material properties (corrosion and wear tests, morphology, chemistry/ composition); comparison of NiW and NiRe with hard chrome (from technological and economic point of view); development of a process control.
Extreme Light Infrastructure Nuclear Physics (ELI-NP)
- The most advanced research facility in the world in the field of photonuclear physics, a new interdisciplinary research field which brings together, for the first time, high-power lasers and nuclear physics.
- The nuclear physics pillar of the Pan-European Distributed Research Infrastructure ELI-Extreme Light Infrastructure.
- The largest investment ever made in scientific research in Romania, co-financed by the European Commission and the Romanian Government from Structural Funds via the European Regional Development Fund (ERDF).
- Implemented by the Horia Hulubei National Institute of Physics and Nuclear Engineering (IFIN-HH), which generates almost 10% of Romania's scientific output. Relevant expertise: Experience with multiple types of Talbot-Lau and Talbot X-ray phase-contrast imaging setups based on grids and other types of X-ray optics. Role in the project: Lead of WP1. Characterise NiW and NiRe grids with phase contrast and dark field contrast X-ray imaging of biomedical interest.
Stellenbosch University CT Facility (SU)
Relevant expertise: This group has significant academic and industry application experience making it a leading X-ray imaging group worldwide. The relevant expertise refers to X-ray imaging specifically in high resolution micro computed tomography (microCT), used for inspection and quantification of defects and flaws in materials, and used widely in materials sciences. The leader of this group is member of the international association for computed tomography, has published over 100 journal articles and is an author of a new review paper on this.
article X-ray computed tomography in the journal "nature reviews methods primers"
Role in the project: Lead of WP 4 and 5. Nickel alloy grids examination, setup of grid based interferometry, exploitation manager.
Microworks GmbH (MW)
Relevant expertise: Microworks’ unique technology (X-Ray lithography) has made progress of X-ray phase- and dark field imaging possible for many industrial and academic institutions. Their close contact to customers provides the right background to define the requirements and specifications for the NiW and NiRe layers, which will be developed within this project.
Role in the project: SME partner. Definition of requirements of NiRe and NiW alloys for use as X-ray absorption material, manufacture and provision of polymer templates for grid structures. Manufacture the grid demonstrator and transfer results to production.
CMF Oberflächendesign GmbH (CMF)
Relevant expertise: CMF has 5 years of experience in electroplating and electroless deposition of different materials in various fields of application. The company's founders, Mr. Grieger and Mr. Konrad, have over 20 years of professional experience in electroless and electroplating deposition.
Role in the project: SME partner. Provides chrome-plated components. Manufactures the hard chrome replacement NiW and NiRe demonstrator and transfers results to production.
Publications "Fokus Forschung" - HS Mittweida
- Neue Nickellegierungsschichten für die Medizintechnik und als Hartchromersatz article
- Aloha auf Hawaii article
- Zukünftige Oberflächen heute gemeinsam gestalten article
- Vier Fäuste aus Mittweida - Branchentreff bei den ZVO Oberflächentagen in Berlin article
- Galvanische Ni-W-Legierungsabscheidung aus wässrigen Systemen als mögliche Hartchromersatzschicht article
- Hundertjahrfeier der Electrodeposition Division der Electrochemical Society (ECS) in Atlanta article
- Neue Nickellegierungen für die Röntgendiagnostik article
Research projects working group
You can find the overview of the research projects of our working group here.